IMO, if you are going to spend $64 on a new drum then it should at least be unlined. If it isn't then you might as well find a used drum to work with. Used or new, the inside needs to start off bare. You could rinse it out pretty good with water provided you are going to season it right away before any rust sets in. You can season it with veggie oil spray. I'll let somebody else chime in on your paint question.
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