If it's not a big hassle (or for comp), definitely trim before brining. The brine does not result in better skin, unlike what it does to the meat. Since you're trimming it and putting it back on, you may as well scrape that skin too!:thumb:
Keep in mind that most chicken available for purchase at most stores is already in solution, so you don't need to brine it. This means that skin has been in solution too, unfortunately.